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Inverse Gaussian process-based corrosion growth modeling and its application in the reliability analysis

Hao QIN, Shenwei ZHANG, Wenxing ZHOU

《结构与土木工程前沿（英文）》 2013年 第7卷 第3期   页码 276-287 doi: 10.1007/s11709-013-0207-9

摘要： This paper describes an inverse Gaussian process-based model to characterize the growth of metal-loss corrosion defects on energy pipelines. The model parameters are evaluated using the Bayesian methodology by combining the inspection data obtained from multiple inspections with the prior distributions. The Markov Chain Monte Carlo (MCMC) simulation techniques are employed to numerically evaluate the posterior marginal distribution of each individual parameter. The measurement errors associated with the ILI tools are considered in the Bayesian inference. The application of the growth model is illustrated using an example involving real inspection data collected from an in-service pipeline in Alberta, Canada. The results indicate that the model in general can predict the growth of corrosion defects reasonably well. Parametric analyses associated with the growth model as well as reliability assessment of the pipeline based on the growth model are also included in the example. The proposed model can be used to facilitate the development and application of reliability-based pipeline corrosion management.

关键词： pipeline     metal-loss corrosion     inverse Gaussian process     measurement error     hierarchical Bayesian     Markov Chain Monte Carlo (MCMC)    

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非并网风电应用中金属材料清洗与防护技术

吴 昊,邹宜哲,白 珂

《中国工程科学》 2015年 第17卷 第3期   页码 41-44

摘要：

为了保证大规模非并网风电装备，特别是金属构件的正常使用，需要对其进行必要的清洗及预防腐处理等前处理，为后续涂层等最终防护工序打下良好材料基础。本文针对金属部件的清洗与预防腐处理技术进行了研究，研发出金属清洗与防护产品，并进行了应用研究。

关键词： 大规模非并网风电；金属；清洗；预防腐；前处理    

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Influence of surface modified mixed metal oxide nanoparticles on the electrochemical and mechanical properties

《化学科学与工程前沿（英文）》 2023年 第17卷 第1期   页码 1-14 doi: 10.1007/s11705-022-2176-9

摘要： Newly synthesized functional nanoparticles, 3-amino-1,2,4-triazole (ATA)/SiO2–TiO2 were introduced to the polyurethane (PU) matrix. Electrochemical techniques were used to investigate the barrier properties of the synthesized PU–ATA/SiO2–TiO2 nanocomposite coated steel specimen. In natural seawater, electrochemical impedance spectroscopy experiments indicated outstanding protective behaviour for the PU–ATA/SiO2–TiO2 coated steel. The coating resistance (Rcoat) of PU–ATA/SiO2–TiO2 was determined to be 2956.90 kΩ·cm–2. The Rcoat of the PU–ATA/SiO2–TiO2 nanocomposite coating was found to be over 50% higher than the PU coating. The current measured along the scratched surface of the PU–ATA/SiO2–TiO2 coating was found to be very low (1.65 nA). The enhanced ATA/SiO2–TiO2 nanoparticles inhibited the entry of electrolytes into the coating interface, as revealed by scanning electron microscopy/energy dispersive X-ray spectroscopy and X-ray diffraction analysis of the degradation products. Water contact angle testing validated the hydrophobic nature of the PU–ATA/SiO2–TiO2 coating (θ = 115.4°). When the concentration of ATA/SiO2−TiO2 nanoparticles was 2 wt %, dynamic mechanical analysis revealed better mechanical properties. Therefore, the newly synthesised PU–ATA/SiO2–TiO2 nanocomposite provided excellent barrier and mechanical properties due to the addition of ATA/SiO2–TiO2 nanoparticles to the polyurethane, which inhibited material degradation and aided in the prolongation of the coated steel’s life.

关键词： SiO2/TiO2 nanoparticle     nanocomposite coatings     dynamic mechanical analysis     electrochemical techniques     corrosion     colloids and interfaces    

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Study on tribological and electrochemistry properties of metal materials in H2O2 solutions

Chengqing YUAN, Li YU, Jian LI, Xinping YAN

《机械工程前沿（英文）》 2012年 第7卷 第1期   页码 93-98 doi: 10.1007/s11465-012-0313-8

摘要：

Hydrogen peroxide (H2O2) is a kind of ideal green propellant. It is crucial to study the wear behavior and failure modes of the metal materials under the strong oxidizing environment of H2O2. This study aims to investigate the wear of rubbing pairs of 2Cr13 stainless steel against 1045 metal in H2O2 solutions, which has a great effect on wear, the decomposition and damage mechanism of materials. The comparison analysis of the friction coefficients, wear mass loss, worn surface topographies and current densities was conducted under different concentrations of H2O2 solutions. There were significant differences in the tribological and electrochemistry properties of the rubbing pairs in different H2O2 solutions.

关键词： hydrogen peroxide     wear     corrosion     wear mechanism    

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On corrosion to stainless steel by calcium chloride with different extender

Lv XU, Yuanyang HU, Liwei WANG, Ruzhu WANG,

《能源前沿（英文）》 2010年 第4卷 第2期   页码 181-184 doi: 10.1007/s11708-009-0065-2

摘要： A calcium chloride solution with a different extender, which is made up of either pure calcium chloride, calcium chloride with expanded graphite, or calcium chloride with activated carbon, acts differently on stainless steel. The mass ratio between calcium chloride with expanded graphite or activated carbon is almost 4∶1, which is demonstrated to be the optimum ratio. The experimental research in this paper reveals that, of the three solutions, which are pure calcium chloride, calcium chloride with expanded graphite, and calcium chloride with activated carbon, the strongest oxidation creation and pitting corrosion happened in the solution of calcium chloride with expanded graphite, the weakest oxidation creation happened in the solution of calcium chloride with activated carbon, and pitting corrosion was stronger than oxidation creation in the solution of pure calcium chloride. This paper gives the reasons for these phenomena. Furthermore, based on theory analysis, multiple means and approaches are provided to prevent stainless steel from further corroding.

关键词： stainless steel     corrosion     calcium chloride     expanded graphite     activated carbon     oxidation creation     pitting corrosion    

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Monitoring corrosion of reinforcement in concrete structures via fiber Bragg grating sensors

Zhupeng ZHENG, Xiaoning SUN, Ying LEI

《机械工程前沿（英文）》 2009年 第4卷 第3期   页码 316-319 doi: 10.1007/s11465-009-0040-y

摘要： Corrosion of steel and rebar in concrete structures is one of the most frequent reasons for civil infrastructure failures. Thus, improving the effective corrosion sensor technology can greatly reduce cost and provide safe structures with long service lives. However, assessing the corrosion condition of rebars is not simple because they are buried in concrete. In this paper, using fiber Bragg grating (FBG), a corrosion sensor for monitoring steel rebars embedded in a concrete structure is developed and validated by experiments. Based on the fact that the volume and diameter of a rebar embedded in concrete will enlarge due to corrosion, an FBG packaged with fiber-reinforced plastics (FRP) is wrapped on the steel bar. During corrosion, the increase in the bar diameter leads to the increase in fiber strain, which can be measured by the shift of the wavelength of FBG. Performances of the corrosion sensor are validated by accelerating corrosion in lab experiments. The corrosion sensor is embedded in a concrete specimen put in a 5% sodium chloride solution with a constant current. Experimental results show that the corrosion sensor can monitor the concurrence of corrosion of rebars in concrete. The corrosion extent can be quantitatively evaluated through the change in the wavelength of FBG. Therefore, the corrosion sensor developed in this paper is feasible for monitoring the early corrosion of rebars in concrete.

关键词： fiber Bragg grating (FBG)     corrosion     concrete structures     accelerated corrosion test    

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Corrosion mechanisms of candidate structural materials for supercritical water-cooled reactor

Lefu ZHANG, Fawen ZHU, Rui TANG

《能源前沿（英文）》 2009年 第3卷 第2期   页码 233-240 doi: 10.1007/s11708-009-0024-y

摘要： Nickel-based alloys, austenitic stainless steel, ferritic/martensitic heat-resistant steels, and oxide dispersion strengthened steel are presently considered to be the candidate structural or fuel-cladding materials for supercritical water-cooled reactor (SCWR), one of the promising generation IV reactor for large-scale electric power production. However, corrosion and stress corrosion cracking of these candidate alloys still remain to be a major problem in the selection of nuclear fuel cladding and other structural materials, such as water rod. Survey of literature and experimental results reveal that the general corrosion mechanism of those candidate materials exhibits quite complicated mechanism in high-temperature and high-pressure supercritical water. Formation of a stable protective oxide film is the key to the best corrosion-resistant alloys. This paper focuses on the mechanism of corrosion oxide film breakdown for SCWR candidate materials.

关键词： supercritical water-cooled reactor     general corrosion     oxide film     corrosion mechanism    

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碳捕集利用与封存中的金属腐蚀问题研究： 进展与挑战

向勇 ,原玉 ,周佩 ,刘广胜 ,吕伟 ,李明星 ,张春霞 ,周庆军 ,赵雪会 ,闫伟

《中国工程科学》 2023年 第25卷 第3期   页码 197-208 doi: 10.15302/J-SSCAE-2023.07.026

摘要：

深入研究碳捕集、利用与封存（CCUS）技术中的金属腐蚀问题产生的机理和影响，对有效应对和解决捕集、运输、利用与封存系统中存在的材料腐蚀失效问题至关重要，为此，本文对CCUS技术存在的金属腐蚀问题研究进展及挑战进行了综述。本文基于CCUS技术各系统腐蚀环境新颖、腐蚀行为特殊、认知程度有限、防护手段相对匮乏等情况，结合CCUS各系统中的腐蚀环境特点，分析了可能存在的金属腐蚀类型及其主要影响因素，并对其带来的挑战进行了梳理，得出了以下主要结论：对于有机胺捕集系统，吸收剂降解机理及降解产物对腐蚀过程的影响较为复杂，部分降解产物对金属腐蚀有抑制作用；密相CO2输送管道的内腐蚀问题不容忽视，控制水分含量是控制该腐蚀问题的关键；CO2驱油利用与封存系统井筒管材在超高CO2分压、碳源杂质、高矿化度地层水、微生物和应力等多因素的长周期耦合作用下，出现腐蚀失效导致CO2泄露的风险很高。最后，本文对未来需迫切开展的研究方向进行了展望，包括不同碳源杂质对各子系统的腐蚀影响研究、长期封存条件下井筒区域材料降解规律研究以及CCUS系统腐蚀防护技术研究等。

关键词： 碳捕集、利用与封存；碳源杂质；腐蚀环境特点；腐蚀影响因素；超临界CO2    

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Corrosion behavior of metallic alloys in molten chloride salts for thermal energy storage in concentrated

Wenjin Ding, Alexander Bonk, Thomas Bauer

《化学科学与工程前沿（英文）》 2018年 第12卷 第3期   页码 564-576 doi: 10.1007/s11705-018-1720-0

摘要：

Recently, more and more attention is paid on applications of molten chlorides in concentrated solar power (CSP) plants as high-temperature thermal energy storage (TES) and heat transfer fluid (HTF) materials due to their high thermal stability limits and low prices, compared to the commercial TES/HTF materials in CSP-nitrate salt mixtures. A higher TES/HTF operating temperature leads to higher efficiency of thermal to electrical energy conversion of the power block in CSP, however causes additional challenges, particularly increased corrosiveness of metallic alloys used as containers and structural materials. Thus, it is essential to study corrosion behaviors and mechanisms of metallic alloys in molten chlorides at operating temperatures (500–800 °C) for realizing the commercial application of molten chlorides in CSP. The results of studies on hot corrosion of metallic alloys in molten chlorides are reviewed to understand their corrosion behaviors and mechanisms under various conditions (e.g., temperature, atmosphere). Emphasis has also been given on salt purification to reduce corrosive impurities in molten chlorides and development of electrochemical techniques to in-situ monitor corrosive impurities in molten chlorides, in order to efficiently control corrosion rates of metallic alloys in molten chlorides to meet the requirements of industrial applications.

关键词： corrosion mechanisms     impurities     metallic corrosion     salt purification     electrochemical techniques    

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Panoramic variation analysis of a family with neurodevelopmental disorders caused by biallelic loss-of-function

《医学前沿（英文）》 doi: 10.1007/s11684-023-1006-x

摘要： Highly clinical and genetic heterogeneity of neurodevelopmental disorders presents a major challenge in clinical genetics and medicine. Panoramic variation analysis is imperative to analyze the disease phenotypes resulting from multilocus genomic variation. Here, a Pakistani family with parental consanguinity was presented, characterized with severe intellectual disability (ID), spastic paraplegia, and deafness. Homozygosity mapping, integrated single nucleotide polymorphism (SNP) array, whole-exome sequencing, and whole-genome sequencing were performed, and homozygous variants in TMEM141 (c.270G>A, p.Trp90*), DDHD2 (c.411+767_c.1249-327del), and LHFPL5 (c.250delC, p.Leu84*) were identified. A Tmem141p.Trp90*/p.Trp90* mouse model was generated. Behavioral studies showed impairments in learning ability and motor coordination. Brain slice electrophysiology and Golgi staining demonstrated deficient synaptic plasticity in hippocampal neurons and abnormal dendritic branching in cerebellar Purkinje cells. Transmission electron microscopy showed abnormal mitochondrial morphology. Furthermore, studies on a human in vitro neuronal model (SH-SY5Y cells) with stable shRNA-mediated knockdown of TMEM141 showed deleterious effect on bioenergetic function, possibly explaining the pathogenesis of replicated phenotypes in the cross-species mouse model. Conclusively, panoramic variation analysis revealed that multilocus genomic variations of TMEM141, DDHD2, and LHFPL5 together caused variable phenotypes in patient. Notably, the biallelic loss-of-function variants of TMEM141 were responsible for syndromic ID.

关键词： neurodevelopmental disorder     autosomal recessive intellectual disability     consanguinity     spastic paraplegia     hearing loss     TMEM141    

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Synergistic effects of sodium hypochlorite disinfection and iron-oxidizing bacteria on early corrosion

《环境科学与工程前沿（英文）》 2022年 第16卷 第6期 doi: 10.1007/s11783-021-1506-3

摘要：

• The early corrosion process in the cast iron pipes was investigated.

关键词： Cast iron pipe corrosion     Drinking water distribution systems     Chlorine disinfection     Iron-oxidizing bacteria     Coupling effects    

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我国腐蚀管理体系研究

马秀敏,朱桂雨,路东柱,段继周,侯保荣

《中国工程科学》 2022年 第24卷 第1期   页码 190-197 doi: 10.15302/J-SSCAE-2022.01.020

摘要：

腐蚀管理关乎安全生产，关乎国民经济，关乎生态文明，关乎资源节约和国家建设。虽然少数行业在腐蚀管理方面已经进行了一些卓有成效的探索和实践，但是总体上腐蚀管理在我国发展十分不平衡，存在着腐蚀管理意识薄弱、专业人才短缺和管理系统不健全等问题。因此，有必要进一步明确腐蚀管理的内涵，明确我国腐蚀管理体系化发展的基本要求，推动腐蚀管理体系化持续健康发展。本文基于中国工程院重点咨询项目“我国腐蚀管理状况与对策战略研究”主要研究成果，阐述了腐蚀管理的内涵及体系化发展的重要意义，分析了我国腐蚀管理的现状及问题，总结提出了腐蚀管理体系基本框架及管理要点，提出了将腐蚀管理纳入国家安全战略，成立腐蚀管理战略研究常设机构；加强腐蚀学科建设，强化人才战略；建立健全腐蚀防护相关法规标准，强化标准意识；加强腐蚀数据库建设，畅通沟通渠道；搭建腐蚀管理信息及大数据交流平台，打造共享管理新模式等对策建议。

关键词： 腐蚀管理，腐蚀管理体系，腐蚀防护，腐蚀控制，腐蚀安全    

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Synthesis of mono and bis-4-methylpiperidiniummethyl-urea as corrosion inhibitors for steel in acidic

Abbas TEIMOURI, Nasrin SOLTANI, Alireza Najafi CHERMAHINI

《化学科学与工程前沿（英文）》 2011年 第5卷 第1期   页码 43-50 doi: 10.1007/s11705-010-0532-7

摘要： Mono and bis-4-methylpiperidiniummethyl urea were synthesized, characterized and used as new corrosion inhibitors of mild steel in the acidic media. Inhibitory effect of two compounds on mild steel surface in the 1 mol·L sulphuric acid has been studied by a series of techniques, such as potentiodynamic polarization, weight loss and quantum chemical calculation methods. Potentiodynamic polarization measurements showed that two inhibitors are mixed type. All measurements showed that inhibition efficiencies enhanced with increase of inhibitor concentration. This reveals that inhibitive actions of inhibitors were mainly due to adsorption on mild steel surface. Density functional (DFT) calculations have been carried out for the title compounds by performing HF and DFT levels of theory using the standard 6-31G* basis set.

关键词： corrosion inhibitors     mild steel     acidic medium     theoretical studies     DFT    

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Corrosion behavior of Fe–Cr–Ni based alloys exposed to molten MgCl2–KCl–NaCl salt with over-addedMg corrosion inhibitor

《化学科学与工程前沿（英文）》 2023年 第17卷 第10期   页码 1608-1619 doi: 10.1007/s11705-023-2349-1

摘要： MgCl2–NaCl–KCl salts mixture shows great potential as a high-temperature (> 700 °C) thermal energy storage material in next-generation concentrated solar power plants. Adding Mg into molten MgCl2–NaCl–KCl salt as a corrosion inhibitor is one of the most effective and cost-effective methods to mitigate the molten salt corrosion of commercial Fe–Cr–Ni alloys. However, it is found in this work that both stainless steel 310 and Incoloy 800H samples were severely corroded after 500 h immersion test at 700 °C when the alloy samples directly contacted with the over-added Mg in the liquid form. The corrosion attack is different from the classical impurity-driven corrosion in molten chloride salts found in previous work. Microscopic analysis indicates that Ni preferentially leaches out of alloy matrix due to the tendency to form MgNi2/Mg2Ni compounds. The Ni-depletion leads to the formation of a porous corrosion layer on both alloys, with the thickness around 204 µm (stainless steel 310) and 1300 µm (Incoloy 800H), respectively. These results suggest that direct contact of liquid Mg with Ni-containing alloys should be avoided during using Mg as a corrosion inhibitor for MgCl2–NaCl–KCl or other chlorides for high temperature heat storage and transfer.

关键词： concentrated solar power (CSP)     Mg corrosion inhibitor     Mg–Ni intermetallic     salt purification     thermal energy storage (TES)    

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Corrosion damage assessment and monitoring of large steel space structures

Bo CHEN, You-Lin XU, Weilian QU,

《结构与土木工程前沿（英文）》 2010年 第4卷 第3期   页码 354-369 doi: 10.1007/s11709-010-0088-0

摘要： Large steel space structures, when exposed to a harsh corrosive environment, are inevitably subjected to atmospheric corrosion and stress corrosion cracking. This paper proposes a framework for assessing the corrosion damage of large steel space structures subjected to both stress corrosion cracking and atmospheric corrosion. The empirical model for estimating atmospheric corrosion based on measured information is briefly introduced. The proposed framework is applied to a real large steel space structure built in the southern coastal area in China to assess its corrosion damage and investigate the effects of atmospheric corrosion on stress corrosion cracking. Based on the results, the conceptual design of the corrosion monitoring system of large steel space structures is finally conducted as the first step for a real corrosion monitoring system.

关键词： large steel space structure     atmospheric corrosion     stress corrosion cracking     corrosion damage     damage assessment     monitoring system    

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标题 作者 时间 类型 操作

Inverse Gaussian process-based corrosion growth modeling and its application in the reliability analysis

Hao QIN, Shenwei ZHANG, Wenxing ZHOU

期刊论文

非并网风电应用中金属材料清洗与防护技术

吴 昊,邹宜哲,白 珂

期刊论文

Influence of surface modified mixed metal oxide nanoparticles on the electrochemical and mechanical properties

期刊论文

Study on tribological and electrochemistry properties of metal materials in H2O2 solutions

Chengqing YUAN, Li YU, Jian LI, Xinping YAN

期刊论文

On corrosion to stainless steel by calcium chloride with different extender

Lv XU, Yuanyang HU, Liwei WANG, Ruzhu WANG,

期刊论文

Monitoring corrosion of reinforcement in concrete structures via fiber Bragg grating sensors

Zhupeng ZHENG, Xiaoning SUN, Ying LEI

期刊论文

Corrosion mechanisms of candidate structural materials for supercritical water-cooled reactor

Lefu ZHANG, Fawen ZHU, Rui TANG

期刊论文

碳捕集利用与封存中的金属腐蚀问题研究： 进展与挑战

向勇 ,原玉 ,周佩 ,刘广胜 ,吕伟 ,李明星 ,张春霞 ,周庆军 ,赵雪会 ,闫伟

期刊论文

Corrosion behavior of metallic alloys in molten chloride salts for thermal energy storage in concentrated

Wenjin Ding, Alexander Bonk, Thomas Bauer

期刊论文

Panoramic variation analysis of a family with neurodevelopmental disorders caused by biallelic loss-of-function

期刊论文

Synergistic effects of sodium hypochlorite disinfection and iron-oxidizing bacteria on early corrosion

期刊论文

我国腐蚀管理体系研究

马秀敏,朱桂雨,路东柱,段继周,侯保荣

期刊论文

Synthesis of mono and bis-4-methylpiperidiniummethyl-urea as corrosion inhibitors for steel in acidic

Abbas TEIMOURI, Nasrin SOLTANI, Alireza Najafi CHERMAHINI

期刊论文

Corrosion behavior of Fe–Cr–Ni based alloys exposed to molten MgCl2–KCl–NaCl salt with over-addedMg corrosion inhibitor

期刊论文

Corrosion damage assessment and monitoring of large steel space structures

Bo CHEN, You-Lin XU, Weilian QU,

期刊论文